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Beilstein J. Org. Chem. 2018, 14, 971–978, doi:10.3762/bjoc.14.82
Graphical Abstract
Figure 1: Structures of pentavalent iodine oxidants 1 and 2, and iodine catalysts 3–13.
Figure 2: Structures of the catalysts 16–25.
Scheme 1: Oxidation of the monovalent iodine derivatives 17 and 3 to the pentavalent iodine derivatives 29 an...
Figure 3: Reaction profile of the oxidation of (a) iodobenzamide 17 and (b) 2-iodobenzoic acid (3) with Oxone®...
Scheme 2: Plausible reaction mechanism for the oxidation of alcohols catalyzed by the 2-iodobenzamides.